When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CF3O2NO2_JPL-2015(2015)_301K_185-340nm(rec).txt |
| NAME: | trifluoromethyl peroxynitrate |
| FORMULA: | CF3O2NO2 |
| AUTHOR(YEAR): | JPL-2015(2015) |
| T: | 301K |
| λ: | 185-340nm(rec) |
| BIBLIOGRAPHY: |
J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18",
JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, 2015 http://jpldataeval.jpl.nasa.gov
|
| COMMENTS: | JPL-2015 recommendation:
185-340 nm, data of
R. Kopitzky, H. Willner, H.-G. Mack, A. Pfeiffer, and H. Oberhammer, "IR and UV absorption cross sections, vibrational analysis, and the molecular structure of trifluoromethyl peroxynitrate, CF3OONO2", Inorg. Chem. 37, 6208-6213 (1998); DOI: 10.1021/ic980776p
The parameterization of the cross section temperature dependence of
F.E. Malanca, M.S. Chiappero, G.A. Argüello, and T.J. Wallington, "Trifluoro methyl peroxynitrate (CF3OONO2): Temperature dependence of the UV absorption spectrum and atmospheric implications", Atmos. Environ. 39, 5051-5057 (2005); DOI: 10.1016/j.atmosenv.2005.05.026,
using the empirical expression
log10 σ = B × T + log10 σ0,
where σ and σ0 are the cross sections in cm2 molecule–1 at temperatures T and 0 K,
has been adopted
The recommended parameters B and σ0 are:
---------------------------------------------------
λ 103 B 1020 σ(0 K)
(nm) (K-1) (cm2 molecule-1)
---------------------------------------------------
290 6.8 1.2×10-2
295 8.3 2.9×10-3
300 10.5 4.4×10-4
305 12 8.4×10-5
310 14 1.9×10-6
315 16.4 2.9×10-6
320 18 6.0×10-7
325 22 3.7×10-8
330 26 1.3×10-9 |
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